Allyl glycidyl ether → Glycidyloxypropyltrimethylsilane

HRID 2297070Notes

Reaction equation

HRID 2297070 reaction equation
[CH2:1]([O:5][CH2:6][CH:7]=[CH2:8])[CH:2]1[O:4][CH2:3]1.[CH3:9][SiH:10]([CH3:12])[CH3:11]>[Pt]>[CH2:1]([O:5][CH2:6][CH2:7][CH2:8][Si:10]([CH3:12])([CH3:11])[CH3:9])[CH:2]1[O:4][CH2:3]1

Participants

4

Reactant 2

HCID 7838Allyl glycidyl etherHCID 70435Trimethylsilane

Product 1

HCID 11816314Glycidyloxypropyltrimethylsilane

Reagents, catalysts & solvents 1

HCID 23939PlatinumCatalyst

Conditions

Temperature
130 °C

Procedure

Allyl glycidyl ether (30.3 g, 0.266 moles) and 3 mg of platinum catalyst are weighed into a 300 mL laboratory autoclave. The autoclave, together with its contents, is cooled in an acetone/dry ice bath in an atmosphere of argon and 19.7 g of trimethylsilane (0.266 moles with a boiling point of 6.7° C.) are siphoned over from the condensed phase. The autoclave is closed and heated to 130° C. At the same time, the internal pressure increases to 7.6 bar and then drops again to 3.2 bar, indicating a reaction.

Workup

  1. customThe autoclave is closed
  2. temperatureAt the same time, the internal pressure increases to 7.6 bar
  3. customa reaction

Sources & evidence

ORD record
ord-0354b13f0ce341b786ac4f100a17fda7
Source dataset
uspto-grants-2002_12
Patent number
US06489498B2

Reaction notes

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