HCID 19360856, compound → Acenaphthene

HRID 2309170Notes

Reaction equation

HRID 2309170 reaction equation
[CH2:1]1[C:11]2=[C:12]3[C:7](=[CH:8][CH:9]=[CH:10]2)[CH:6]=[CH:5][CH:4]=[C:3]3[CH2:2]1.ClCCl>O(C1C=CC(C(Cl)=O)=CC=1)C1C=CC=CC=1.FC(F)(F)C(O)=O>[CH2:2]1[C:3]2=[C:12]3[C:7](=[CH:6][CH:5]=[CH:4]2)[CH:8]=[CH:9][CH:10]=[C:11]3[CH2:1]1

Participants

4

Reactant 1

HCID 19360856HCID 19360856, compound

Product 1

HCID 6734Acenaphthene

Reagents, catalysts & solvents 2

HCID 741934-Phenoxybenzoyl chlorideCatalystHCID 6422Trifluoroacetic acidSolvent

Procedure

In a small vial, about 200 mg (12 drops) of crude p-phenoxybenzoyl chloride is dissolved in about 2 ml of trifluoroacetic acid. To this yellowish-brown solution is added three drops of 5 wt % acenaphthene/dichloromethane solution. The vial is swirled to mix the contents thoroughly and the color is immediately observed.

Workup

  1. additionto mix the contents thoroughly

Sources & evidence

ORD record
ord-b831057a6d1847769381f1a6662be84e
Source dataset
uspto-grants-1987_09
Patent number
US04693851

Reaction notes

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