Diisopropylamine → Lithium ion

HRID 2318549Notes

Reaction equation

HRID 2318549 reaction equation
[CH2:1]([CH2:2][CH2:3][CH3:4])[Li:5].[CH2:42]1[O:43][CH2:44][CH2:45][CH2:46]1.[CH2:6]([CH3:7])[O:8][C:9]1=[CH:10][C:11](=[O:15])[CH2:12][CH2:13][CH2:14]1.[CH3:29][CH2:30][CH2:31][CH2:32][CH2:33][CH3:34].[CH3:47][N:48]([CH3:49])[P:50]([N:51]([CH3:52])[CH3:53])([N:54]([CH3:55])[CH3:56])=[O:57].[CH:16]([CH3:17])([CH3:18])[N-:19][CH:20]([CH3:21])[CH3:22].[CH:35]([NH:36][CH:37]([CH3:38])[CH3:39])([CH3:40])[CH3:41].[I:24][CH2:25][CH2:26][CH2:27][CH3:28].[Li+:23]>>[CH2:1]([CH2:2][CH2:3][CH3:4])[CH:12]1[C:11](=[O:15])[CH:10]=[C:9]([O:8][CH2:6][CH3:7])[CH2:14][CH2:13]1.[CH:16]([CH3:17])([CH3:18])[N-:19][CH:20]([CH3:21])[CH3:22].[Li+:5]

Participants

12

Reactant 9

HCID 7912DiisopropylamineHCID 8028TetrahydrofuranHCID 8058HexaneHCID 10962Butyl iodideHCID 12679HexamethylphosphoramideHCID 28486Lithium ionHCID 792163-Ethoxycyclohex-2-ene-1-oneHCID 5062348DiisopropylamideHCID 178418339Butyllithium

Product 3

HCID 28486Lithium ionHCID 5062348DiisopropylamideHCID 20263887HCID 20263887, compound

Sources & evidence

ORD record
ord-5e238c3dfa784900aeecb39401568a9e
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (10/10)

Reaction notes

Loading…