Acetate → Dicyclohexyl(2',6'-dimethoxy[1,1'-biphenyl]-2-YL)phosphine oxide

HRID 2320126Notes

Reaction equation

HRID 2320126 reaction equation
[C:14]([O-:15])(=[O:16])[O-:17].[CH2:70]1[O:71][CH2:72][CH2:73][O:74][CH2:75]1.[CH3:61][CH2:62][O:63][C:64](=[O:65])[CH3:66].[CH3:68][OH:69].[CH:20]1([P:26]([c:27]2[c:28](-[c:33]3[c:34]([O:41][CH3:42])[cH:35][cH:36][cH:37][c:38]3[O:39][CH3:40])[cH:29][cH:30][cH:31][cH:32]2)[CH:43]2[CH2:44][CH2:45][CH2:46][CH2:47][CH2:48]2)[CH2:21][CH2:22][CH2:23][CH2:24][CH2:25]1.[Cl:1][c:2]1[cH:3][cH:4][c:5](-[c:6]2[cH:7][cH:8][cH:9][cH:10][cH:11]2)[cH:12][cH:13]1.[Cs+:18].[Cs+:19].[NH2:50][NH2:51].[O-:53][C:54]([CH3:55])=[O:56].[O-:57][C:58]([CH3:59])=[O:60].[OH2:49].[OH2:67].[Pd+2:52]>>[O:15]=[P:26]([CH:20]1[CH2:21][CH2:22][CH2:23][CH2:24][CH2:25]1)([c:27]1[c:28](-[c:33]2[c:34]([O:41][CH3:42])[cH:35][cH:36][cH:37][c:38]2[O:39][CH3:40])[cH:29][cH:30][cH:31][cH:32]1)[CH:43]1[CH2:44][CH2:45][CH2:46][CH2:47][CH2:48]1

Participants

12

Reactant 11

HCID 175Acetate2×HCID 887MethanolHCID 962Water2×HCID 8857Ethyl AcetateHCID 9321HydrazineHCID 163234-ChlorobiphenylHCID 19660Carbonate IonHCID 312751,4-DioxaneHCID 104967Cesium cation2×HCID 105144Allyl(1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene)chloropalladium(II)HCID 112698722-Dicyclohexylphosphino-2',6'-dimethoxybiphenyl

Product 1

HCID 67122844Dicyclohexyl(2',6'-dimethoxy[1,1'-biphenyl]-2-YL)phosphine oxide

Sources & evidence

ORD record
ord-f93f79ea7f7b4f07b3d7555f7ffc63a3
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (10/10)

Reaction notes

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