Ammonium → (+/-)-2-Azido-6-methyl-4-(3-nitropyridin-4-yl)cyclohex-3-enol

HRID 2333380Notes

Reaction equation

HRID 2333380 reaction equation
[CH3:1][CH:2]1[CH:3]=[CH:4][CH:5]=[C:6]([c:8]2[c:9]([N+:14](=[O:15])[O-:16])[cH:10][n:11][cH:12][cH:13]2)[CH2:7]1.[CH3:37][CH2:38][OH:39].[Cl-:32].[Cl:34][CH2:35][Cl:36].[N-:29]=[N+:30]=[N-:31].[NH4+:33].[Na+:28].[OH2:40].[OH:17][O:18][C:19]([c:20]1[cH:21][c:22]([Cl:23])[cH:24][cH:25][cH:26]1)=[O:27]>>[CH3:1][CH:2]1[CH:3]([OH:17])[CH:4]([N:29]=[N+:30]=[N-:31])[CH:5]=[C:6]([c:8]2[c:9]([N+:14](=[O:15])[O-:16])[cH:10][n:11][cH:12][cH:13]2)[CH2:7]1

Participants

10

Reactant 9

HCID 223AmmoniumHCID 312ChlorideHCID 702EthanolHCID 923Sodium ionHCID 962WaterHCID 6344DichloromethaneHCID 33558AzideHCID 70297m-Chloroperbenzoic acidHCID 59226560HCID 59226560, compound

Product 1

HCID 72238239(+/-)-2-Azido-6-methyl-4-(3-nitropyridin-4-yl)cyclohex-3-enol

Sources & evidence

ORD record
ord-a93fa694eaec4aedaf89672663cb77f2
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (10/10)

Reaction notes

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