Triphenylphosphine → HCID 178491412, compound

HRID 2338248Notes

Reaction equation

HRID 2338248 reaction equation
[Cu:86][I:87].[I:1][c:2]1[c:3](=[O:38])[nH:4][c:5](=[O:37])[n:6]([CH:7]2[CH2:8][CH:9]([OH:10])[CH:11]([CH2:12][O:13][C:14]([c:15]3[cH:16][cH:17][c:18]([O:21][CH3:22])[cH:19][cH:20]3)([c:23]3[cH:24][cH:25][cH:26][cH:27][cH:28]3)[c:29]3[cH:30][cH:31][cH:32][cH:33][cH:34]3)[O:35]2)[cH:36]1.[Pd:45]([Cl:46])[Cl:47].[Si:39]([CH3:40])([CH3:41])([CH3:42])[C:43]#[CH:44].[c:48]1([P:49]([c:50]2[cH:51][cH:52][cH:53][cH:54][cH:55]2)[c:56]2[cH:57][cH:58][cH:59][cH:60][cH:61]2)[cH:62][cH:63][cH:64][cH:65][cH:66]1.[c:67]1([P:68]([c:69]2[cH:70][cH:71][cH:72][cH:73][cH:74]2)[c:75]2[cH:76][cH:77][cH:78][cH:79][cH:80]2)[cH:81][cH:82][cH:83][cH:84][cH:85]1>>[c:2]1([C:44]#[C:43][Si:39]([CH3:40])([CH3:41])[CH3:42])[c:3](=[O:38])[nH:4][c:5](=[O:37])[n:6]([CH:7]2[CH2:8][CH:9]([OH:10])[CH:11]([CH2:12][O:13][C:14]([c:15]3[cH:16][cH:17][c:18]([O:21][CH3:22])[cH:19][cH:20]3)([c:23]3[cH:24][cH:25][cH:26][cH:27][cH:28]3)[c:29]3[cH:30][cH:31][cH:32][cH:33][cH:34]3)[O:35]2)[cH:36]1

Participants

6

Reactant 5

HCID 11776Triphenylphosphine2×HCID 24290Palladium ChlorideHCID 24350Copper(1+) iodide; Copper(I) iodide; Cuprous iodide; Cuprous iodide (CuI)HCID 66111TrimethylsilylacetyleneHCID 178491423HCID 178491423, compound

Product 1

HCID 178491412HCID 178491412, compound

Sources & evidence

ORD record
ord-726a44ddf6ee4aaaa687d14859ccf0e1
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (10/10)

Reaction notes

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