Bromide ion → Benzyl 4-bromotetrahydro-1(2H)-pyridinecarboxylate

HRID 2349462Notes

Reaction equation

HRID 2349462 reaction equation
[Br-:21].[CH2:22]([c:23]1[cH:24][cH:25][cH:26][cH:27][cH:28]1)[O:29][C:30](=[O:31])[N:32]1[CH2:33][CH2:34][CH:35]([OH:38])[CH2:36][CH2:37]1.[CH2:39]1[O:40][CH2:41][CH2:42][CH2:43]1.[Li+:20].[c:1]1([P:2]([c:3]2[cH:4][cH:5][cH:6][cH:7][cH:8]2)[c:9]2[cH:10][cH:11][cH:12][cH:13][cH:14]2)[cH:15][cH:16][cH:17][cH:18][cH:19]1>>[Br:21][CH:35]1[CH2:34][CH2:33][N:32]([C:30]([O:29][CH2:22][c:23]2[cH:24][cH:25][cH:26][cH:27][cH:28]2)=[O:31])[CH2:37][CH2:36]1

Participants

6

Reactant 5

HCID 259Bromide ionHCID 8028TetrahydrofuranHCID 11776TriphenylphosphineHCID 28486Lithium ionHCID 2794620Benzyl 4-Hydroxy-1-piperidinecarboxylate

Product 1

HCID 2776275Benzyl 4-bromotetrahydro-1(2H)-pyridinecarboxylate

Sources & evidence

ORD record
ord-50b3aee5f5a5412b89127cddc6f01be4
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (10/10)

Reaction notes

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