Ammonium Acetate → HCID 14745924, compound

HRID 2372940Notes

Reaction equation

HRID 2372940 reaction equation
[Cl:1]/[C:2](/[C:11]([O:13][CH:14]([CH3:16])[CH3:15])=[O:12])=[C:3](\Cl)/[C:4]([O:6][CH:7]([CH3:9])[CH3:8])=[O:5].C([O-])(=O)C.[NH4+:21]>CN(C)C=O>[NH2:21]/[C:3](/[C:4]([O:6][CH:7]([CH3:9])[CH3:8])=[O:5])=[C:2](\[Cl:1])/[C:11]([O:13][CH:14]([CH3:16])[CH3:15])=[O:12]

Participants

4

Reactant 2

HCID 517165Ammonium AcetateHCID 19902725HCID 19902725, compound

Product 1

HCID 14745924HCID 14745924, compoundYield 118.7%

Reagents, catalysts & solvents 1

HCID 6228DimethylformamideSolvent

Procedure

26.9 g (0.1 mol) of diisopropyl dichloromaleate, 19.27 g (0.25 mol) of ammonium acetate and 40 ml of dimethylformamide were reacted under the same conditions as described in Example 1. 29.65 g (85.6% yield) of diisopropyl aminochloromaleate were obtained as a reddish-yellow, viscous liquid (purity according to GC analysis 83%).

Sources & evidence

ORD record
ord-70f4b319e7f645c79346629a4a3d254a
Source dataset
uspto-grants-1992_03
Patent number
US05101067

Reaction notes

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