Perylene → TCNQ perylene

HRID 2380549노트

반응식

HRID 2380549 반응식
[CH:1]1[C:11](=[C:12]([C:15]#[N:16])[C:13]#[N:14])[CH:10]=[CH:9][C:3](=[C:4]([C:7]#[N:8])[C:5]#[N:6])[CH:2]=1.[CH:17]1[C:34]2=[C:35]3[C:24]([C:25]4[C:36]5[C:29](=[CH:30][CH:31]=[CH:32][C:33]2=5)[CH:28]=[CH:27][CH:26]=4)=[CH:23][CH:22]=[CH:21][C:20]3=[CH:19][CH:18]=1>C(Cl)(Cl)Cl>[CH:2]1[C:3](=[C:4]([C:5]#[N:6])[C:7]#[N:8])[CH:9]=[CH:10][C:11](=[C:12]([C:13]#[N:14])[C:15]#[N:16])[CH:1]=1.[CH:32]1[C:33]2=[C:36]3[C:25]([C:24]4[C:35]5[C:20](=[CH:19][CH:18]=[CH:17][C:34]2=5)[CH:21]=[CH:22][CH:23]=4)=[CH:26][CH:27]=[CH:28][C:29]3=[CH:30][CH:31]=1

참가 물질

4

반응물 2

HCID 9142PeryleneHCID 73697Tetracyanoquinodimethane

생성물 1

HCID 86747618TCNQ perylene

시약·촉매·용매 1

HCID 6212Chloroform용매

실험 절차

Then 1 g of equimolar mixture of TCNQ and perylene was dissolved in 250 ml of chloroform while slightly heatig the solvent. After allowing to cool, the solution was filtered through Teflon membrane filter with a pore size of 1 μm, and the filtrate was slowly cooled from the room temperature to -20° C. at a rate of about 1° C./hr to obtain several purple-black crystals in the form of an elongated plate (the largest one sized 5 cm length, ×1 mm width ×400 μm thickness). After collecting the crystals by filtration, the crystals were washed with ether and was dried in the air. The crystals were confirmed to be single crystals by observing them with a polarizing microscope under closed nicols. [Processing of the charge-transfer crystals into third-order nonlinear optical element]

후처리

  1. temperatureto cool
  2. filtrationthe solution was filtered through Teflon membrane
  3. filtrationfilter with a pore size of 1 μm
  4. temperaturethe filtrate was slowly cooled from the room temperature to -20° C. at a rate of about 1° C./hr
  5. customto obtain several purple-black crystals in the form of an elongated plate (the largest one sized 5 cm length, ×1 mm width ×400 μm thickness)
  6. customAfter collecting the crystals
  7. filtrationby filtration
  8. washthe crystals were washed with ether
  9. customwas dried in the air

출처 및 근거

ORD 기록
ord-461a5714ba20473198859238a3b9c0e7
출처 데이터셋
uspto-grants-1994_11
특허 번호
US05368782

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