Methyl Acrylate → HCID 20444819, compound

HRID 2418658Notes

Reaction equation

HRID 2418658 reaction equation
[CH3:1][O:2][C:3](=[O:6])[CH:4]=[CH2:5].[CH2:7]([CH:9]([CH2:12][CH2:13][CH2:14][CH3:15])[CH2:10][NH2:11])[CH3:8]>>[C:3]([CH2:4][CH2:5][NH:11][CH2:10][CH:9]([CH2:7][CH3:8])[CH2:12][CH2:13][CH2:14][CH3:15])([O:2][CH3:1])=[O:6]

Participants

3

Reactant 2

HCID 7294Methyl AcrylateHCID 77192-Ethylhexylamine

Product 1

HCID 20444819HCID 20444819, compound

Conditions

Temperature
35 °C

Procedure

While stirring at a temperature of 20° C., 90.3 grams (1.05 mole) of methylacrylate were dripped into 129 grams (1 mole) of 2-ethylhexylamine within a period of 30 minutes. The temperature was increased to 35° C. The mixture was stirred at 100° C. for 2 hours and was subsequently degassed at 50° C. under a high vacuum for 1 hour. The remaining residue was 210 grams (98 percent of theory) liquid N-(2'-carbomethoxy-ethyl)-2-ethylhexylamine. The 60 MHz-Nuclear Magnetic Resonance Spectrum s 3.7 ppm COOCH3 ; m 2.9 ppm; m 2.5 ppm; 0.7 to 1.5 ppm confirms the structure.

Workup

  1. customwas subsequently degassed at 50° C. under a high vacuum for 1 hour

Sources & evidence

ORD record
ord-6c04e918673e4c8585d91eb41873cdb1
Source dataset
uspto-grants-1984_09
Patent number
US04473491

Reaction notes

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