4-Hydroxybenzaldehyde → HCID 86632834, compound

HRID 2426757Notes

Reaction equation

HRID 2426757 reaction equation
C(P(CCCC)CCCC)CCC.N(C(N1CCCCC1)=O)=NC(N1CCCCC1)=O.[Si:32]([O:39][C:40]1[CH:45]=[CH:44][C:43]([C:46]2[C:51]([CH3:52])=[CH:50][CH:49]=[CH:48][C:47]=2[CH3:53])=[CH:42][C:41]=1[CH2:54][OH:55])([C:35]([CH3:38])([CH3:37])[CH3:36])([CH3:34])[CH3:33].O[C:57]1[CH:64]=[CH:63][C:60]([CH:61]=[O:62])=[CH:59][CH:58]=1>C1COCC1>[Si:32]([O:39][C:40]1[CH:45]=[CH:44][C:43]([C:46]2[C:51]([CH3:52])=[CH:50][CH:49]=[CH:48][C:47]=2[CH3:53])=[CH:42][C:41]=1[CH2:54][O:55][C:59]1[CH:58]=[CH:57][CH:64]=[CH:63][C:60]=1[CH:61]=[O:62])([C:35]([CH3:38])([CH3:37])[CH3:36])([CH3:34])[CH3:33]

Participants

6

Reactant 4

HCID 1264-HydroxybenzaldehydeHCID 13831TributylphosphineHCID 730421,1'-(Azodicarbonyl)dipiperidineHCID 67250414HCID 67250414, compound

Product 1

HCID 86632834HCID 86632834, compound

Reagents, catalysts & solvents 1

HCID 8028TetrahydrofuranSolvent

Procedure

Tributylphosphine and 1,1′-(azodicarbonyl)dipiperidine were added to a THF solution of (4-{[tert-butyl(dimethyl)silyl]oxy}-2′,6′-dimethylbiphenyl-3-yl)methanol and 4-hydroxybenzaldehyde, followed by stirring at room temperature for 14 hours to obtain 4-[(4-{[tert-butyl(dimethyl)silyl]oxy}-2′,6′-dimethylbiphenyl-3-yl)methoxybenzaldehyde.

Sources & evidence

ORD record
ord-f01226b6cffd47de99566e84eb63a3c8
Source dataset
uspto-grants-2011_06
Patent number
US07968552B2

Reaction notes

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