Sodium Iodide → HCID 178504101, compound

HRID 258490Notes

Reaction equation

HRID 258490 reaction equation
[CH3:1][S:2][C:3]([P:5](=[O:12])([O:9][CH2:10][CH3:11])[O:6]CC)=[S:4].[I-].[Na+:14]>O1CCCC1>[CH3:1][S:2][C:3]([P:5](=[O:6])([OH:12])[OH:9])=[S:4].[CH2:10]([Na:14])[CH3:11]

Participants

4

Reactant 2

HCID 5238Sodium IodideHCID 14364274HCID 14364274, compound

Product 1

HCID 178504101HCID 178504101, compound

Reagents, catalysts & solvents 1

HCID 8028TetrahydrofuranSolvent

Procedure

To a solution of 2.3 parts of diethyl (methylthio)thiocarbonylphosphonate in 50 parts of dry tetrahydrofuran was added 1.5 parts of sodium iodide. The solution was stirred for 18 hours at room temperature, then warmed on a steam bath for one-half hour. The desired orange ethyl sodium (methylthio)thiocarbonylphosphonate was then filtered, m.p. 288° d.

Workup

  1. temperaturewarmed on a steam bath for one-half hour
  2. filtrationThe desired orange ethyl sodium (methylthio)thiocarbonylphosphonate was then filtered

Sources & evidence

ORD record
ord-c4a904e984e44e558650cd8179fd3d6d
Source dataset
uspto-grants-1977_07
Patent number
US04033749

Reaction notes

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