Iodine → Prop-2-enoic acid--2-ethylhexyl prop-2-enoate (1/1)

HRID 261129Notes

Reaction equation

HRID 261129 reaction equation
COC1[CH:12]=[CH:11][C:10]2[C:5](=[C:6]([C@@H:13]([OH:24])[C@H:14]3N4C[C@H](C=C)[C@@H](CC4)[CH2:15]3)[CH:7]=[CH:8]N=2)C=1.[CH3:25]O.II.I.C([O:32][CH2:33][CH2:34]O)C>C(O)CCCCCCCCC>[C:33]([O:24][CH2:13][CH:6]([CH2:7][CH3:8])[CH2:5][CH2:10][CH2:11][CH3:12])(=[O:32])[CH:34]=[CH2:25].[C:13]([OH:24])(=[O:32])[CH:14]=[CH2:15]

Participants

7

Reactant 5

HCID 807IodineHCID 887MethanolHCID 8076Glycol monoethyl etherHCID 24841Hydrogen iodideHCID 3034034Quinine

Product 1

HCID 168301Prop-2-enoic acid--2-ethylhexyl prop-2-enoate (1/1)

Reagents, catalysts & solvents 1

HCID 81741-DecanolSolvent

Procedure

A copolymer of 2-ethylhexyl acrylate/acrylic acid, 50%/50% by weight was prepared. 42.5 grams of the solution of the copolymer was prepared as a 25% by weight solution in 2-ethoxyethanol to which was added 3.75 grams of quinine bisulphate and 8.50 grams of methanol. As in Example 1, an alcoholic solution of a plasticizer, iodine, and hydriodic acid was reacted with the above ingredients to form a wet paste. The dried paste, using heat to aid dispersion, was then suspended in decyl alcohol. The substance was placed in a light valve and satisfactory operation was achieved.

Workup

  1. customto form a wet paste
  2. temperatureThe dried paste, using heat
  3. customThe substance was placed in a light valve

Sources & evidence

ORD record
ord-7ab4e7344ee647d68253576063768233
Source dataset
uspto-grants-1979_08
Patent number
US04164365

Reaction notes

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