Sodium Iodide → HCID 178504101, compound

HRID 267646Notes

Reaction equation

HRID 267646 reaction equation
[CH3:1][S:2][C:3]([P:5](=[O:12])([O:9][CH2:10][CH3:11])[O:6]CC)=[S:4].[I-].[Na+:14]>O1CCCC1>[CH3:1][S:2][C:3]([P:5](=[O:6])([OH:12])[OH:9])=[S:4].[CH2:10]([Na:14])[CH3:11]

Participants

4

Reactant 2

HCID 5238Sodium IodideHCID 14364274HCID 14364274, compound

Product 1

HCID 178504101HCID 178504101, compound

Reagents, catalysts & solvents 1

HCID 8028TetrahydrofuranSolvent

Procedure

To a solution of 2.3 parts of diethyl (methylthio)-thiocarbonylphosphonate in 50 parts of dry tetrahydrofuran was added 1.5 parts of sodium iodide. The solution was stirred for 18 hours at room temperature, then warmed on a steam bath for one-half hour. The desired orange ethyl sodium (methylthio)thiocarbonylphosphonate was then filtered, m.p. 288°d.

Workup

  1. temperaturewarmed on a steam bath for one-half hour
  2. filtrationThe desired orange ethyl sodium (methylthio)thiocarbonylphosphonate was then filtered

Sources & evidence

ORD record
ord-9f8bd435296d48969ae82dc4e6e0d957
Source dataset
uspto-grants-1976_03
Patent number
US03943201

Reaction notes

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