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HRID267916

反应详情

EQUATION

反应方程式

HRID 267916 的结构方程式

REACTANTS

反应物

3
结构：O=P(Cl)(Cl)Cl
HCID24813

Phosphoric trichloride

Cl3OP

结构：CC1CCC(=O)N1
HCID66055

5-Methyl-2-pyrrolidone

C5H9NO

结构：COc1ccc2c(c1)Nc1ccccc1S2
HCID74490

Methyl phenothiazin-2-yl ether

C13H11NOS

PRODUCTS

生成物

1
结构：COc1ccc2c(c1)N(C1=CCC(C)N1C1=NC(C)CC1)c1ccccc1S2.Cl
HCID20307135

未命名化合物

收率 8.6%

AUXILIARIES

试剂、催化剂与溶剂

1
结构：ClCCCl
溶剂HCID11

1,2-Dichloroethane

C2H4Cl2

PROCEDURE

实验过程

Reaction of 5-methyl-2-pyrrolidinone, 2-methoxyphenothiazine and phosphorus oxychloride in 1,2-dichloroethane according to the procedure of Example 4 affords 2-METHOXY-10-[5-METHYL-1-(5-METHYL-1-PYRROLIN-2-YL)-2-PYRROLIN-2-YL]PHENOTHIAZINE HYDROCHLORIDE (8.6% yield), m.p. 236.5°-238.5° C. (corr.), from ethanol-ether.