Dimethylamine → Diethylamine

HRID 268525Notes

Reaction equation

HRID 268525 reaction equation
ClCCCC(C1C=[CH:9][C:10]2[N:11]([CH2:26][CH3:27])[C:12]3[C:17](C=2C=1)=CC(C(=O)CCCCl)=C[CH:13]=3)=O.CNC.Cl[CH2:32][CH2:33][CH2:34][CH2:35][C:36]([C:38]1[CH:39]=[CH:40][C:41]2[N:42]([CH3:58])[C:43]3[C:48]([C:49]=2[CH:50]=1)=[CH:47][C:46]([C:51](=[O:57])[CH2:52][CH2:53][CH2:54][CH2:55]Cl)=[CH:45][CH:44]=3)=[O:37].C[N:60]1[C:72]2C=CC=C[C:67]=2C2[C:61]1=[CH:62]C=CC=2.ClCCCCC(Cl)=O>>[CH2:10]([NH:11][CH2:12][CH3:13])[CH3:9].[CH2:26]([N:11]([CH2:12][CH3:17])[CH2:32][CH2:33][CH2:34][CH2:35][C:36]([C:38]1[CH:39]=[CH:40][C:41]2[N:42]([CH3:58])[C:43]3[C:48]([C:49]=2[CH:50]=1)=[CH:47][C:46]([C:51](=[O:57])[CH2:52][CH2:53][CH2:54][CH2:55][N:60]([CH2:72][CH3:67])[CH2:61][CH3:62])=[CH:45][CH:44]=3)=[O:37])[CH3:27]

Participants

7

Reactant 5

HCID 674DimethylamineHCID 15142N-MethylcarbazoleHCID 740895-Chlorovaleryl chlorideHCID 123317903,6-Bis(4-chlorobutyryl)-N-ethylcarbazoleHCID 215523123,6-bis(5-chlorovaleryl)-N-methylcarbazole

Product 2

HCID 8021DiethylamineHCID 215523593,6-bis(5-diethylaminovaleryl)-N-methylcarbazole

Procedure

Following the procedure of Example 32, only substituting respectively for 3,6-bis(4-chlorobutyryl)-N-ethylcarbazole and dimethylamine the appropriate molar equivalent amount of 3,6-bis(5-chlorovaleryl)-N-methylcarbazole, prepared from N-methylcarbazole and 5-chlorovaleryl chloride, and an excess of diethylamine, 3,6-bis(5-diethylaminovaleryl)-N-methylcarbazole is obtained.

Sources & evidence

ORD record
ord-e563b236db204950bf679886ff1cad90
Source dataset
uspto-grants-1976_03
Patent number
US03947593

Reaction notes

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