HRID268525

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID674

Dimethylamine

C2H7N

HCID15142

9H-Carbazole, 9-methyl-

C13H11N

HCID74089

Valeryl chloride, 5-chloro-

C5H8Cl2O

结构：CCn1c2ccc(C(=O)CCCCl)cc2c2cc(C(=O)CCCCl)ccc21

HCID12331790

1,1'-(9-Ethyl-9H-carbazole-3,6-diyl)bis(4-chlorobutan-1-one)

C22H23Cl2NO2

结构：Cn1c2ccc(C(=O)CCCCCl)cc2c2cc(C(=O)CCCCCl)ccc21

HCID21552312

未命名化合物

PRODUCTS

生成物

HCID8021

Diethylamine

C4H11N

结构：CCN(CC)CCCCC(=O)c1ccc2c(c1)c1cc(C(=O)CCCCN(CC)CC)ccc1n2C

HCID21552359

未命名化合物

PROCEDURE

实验过程

Following the procedure of Example 32, only substituting respectively for 3,6-bis(4-chlorobutyryl)-N-ethylcarbazole and dimethylamine the appropriate molar equivalent amount of 3,6-bis(5-chlorovaleryl)-N-methylcarbazole, prepared from N-methylcarbazole and 5-chlorovaleryl chloride, and an excess of diethylamine, 3,6-bis(5-diethylaminovaleryl)-N-methylcarbazole is obtained.

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-e563b236db204950bf679886ff1cad90
来源数据集: uspto-grants-1976_03
DOI: 10.6084/m9.figshare.5104873.v1
专利: US03947593
来源说明: uspto-grants-1976_03

反应 SMILES

ClCCCC(C1C=[CH:9][C:10]2[N:11]([CH2:26][CH3:27])[C:12]3[C:17](C=2C=1)=CC(C(=O)CCCCl)=C[CH:13]=3)=O.CNC.Cl[CH2:32][CH2:33][CH2:34][CH2:35][C:36]([C:38]1[CH:39]=[CH:40][C:41]2[N:42]([CH3:58])[C:43]3[C:48]([C:49]=2[CH:50]=1)=[CH:47][C:46]([C:51](=[O:57])[CH2:52][CH2:53][CH2:54][CH2:55]Cl)=[CH:45][CH:44]=3)=[O:37].C[N:60]1[C:72]2C=CC=C[C:67]=2C2[C:61]1=[CH:62]C=CC=2.ClCCCCC(Cl)=O>>[CH2:10]([NH:11][CH2:12][CH3:13])[CH3:9].[CH2:26]([N:11]([CH2:12][CH3:17])[CH2:32][CH2:33][CH2:34][CH2:35][C:36]([C:38]1[CH:39]=[CH:40][C:41]2[N:42]([CH3:58])[C:43]3[C:48]([C:49]=2[CH:50]=1)=[CH:47][C:46]([C:51](=[O:57])[CH2:52][CH2:53][CH2:54][CH2:55][N:60]([CH2:72][CH3:67])[CH2:61][CH3:62])=[CH:45][CH:44]=3)=[O:37])[CH3:27]