Potassium Cation → 4-Cyano-1-(2-trimethylsilanyl-ethoxymethyl)-1H-imidazole-2-carboxylic acid (4-bromo-2-cyclohex-1-enyl-phenyl)-amide

HRID 288514Notes

Reaction equation

HRID 288514 reaction equation
[Br:1][c:2]1[cH:3][c:4]([C:9]2=[CH:10][CH2:11][CH2:12][CH2:13][CH2:14]2)[c:5]([NH2:8])[cH:6][cH:7]1.[Br:41][P+:42]([N:43]1[CH2:44][CH2:45][CH2:46][CH2:47]1)([N:48]1[CH2:49][CH2:50][CH2:51][CH2:52]1)[N:53]1[CH2:54][CH2:55][CH2:56][CH2:57]1.[C:16](#[N:17])[c:18]1[n:19][c:20]([C:31](=[O:32])[O-:33])[n:21]([CH2:23][O:24][CH2:25][CH2:26][Si:27]([CH3:28])([CH3:29])[CH3:30])[cH:22]1.[CH3:67][N:68]([CH3:69])[CH:70]=[O:71].[CH3:72][CH2:73][O:74][C:75]([CH3:76])=[O:77].[CH:58]([N:59]([CH2:60][CH3:61])[CH:62]([CH3:63])[CH3:64])([CH3:65])[CH3:66].[K+:15].[P-:34]([F:35])([F:36])([F:37])([F:38])([F:39])[F:40]>>[Br:1][c:2]1[cH:3][c:4]([C:9]2=[CH:10][CH2:11][CH2:12][CH2:13][CH2:14]2)[c:5]([NH:8][C:31]([c:20]2[n:19][c:18]([C:16]#[N:17])[cH:22][n:21]2[CH2:23][O:24][CH2:25][CH2:26][Si:27]([CH3:28])([CH3:29])[CH3:30])=[O:32])[cH:6][cH:7]1

Participants

9

Reactant 8

HCID 813Potassium CationHCID 6228DimethylformamideHCID 8857Ethyl AcetateHCID 9886HexafluorophosphateHCID 81531DiisopropylethylamineHCID 2733180Bromotripyrrolidin-1-ylphosphoniumHCID 591285844-Cyano-1-(2-trimethylsilylethoxymethyl)imidazole-2-carboxylateHCID 594575414-Bromo-2-cyclohex-1-enyl-phenylamine

Product 1

HCID 594575324-Cyano-1-(2-trimethylsilanyl-ethoxymethyl)-1H-imidazole-2-carboxylic acid (4-bromo-2-cyclohex-1-enyl-phenyl)-amide

Sources & evidence

ORD record
ord-ae05470ea8a54b0da57e14bdd65db107
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (8/10)

Reaction notes

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