Ammonium → 5,7-dimethyl-8-methoxy-9-(2,2-diethoxyethyl)-1,2,3,4-tetrahydro-9H-fluorene

HRID 301173Notes

Reaction equation

HRID 301173 reaction equation
[CH2:29]([CH3:30])[O:31][CH:32]([CH2:33][Br:34])[O:35][CH2:36][CH3:37].[CH2:7]([Li:8])[CH2:9][CH2:10][CH3:11].[CH3:12][c:13]1[c:14]2[c:22]([c:23]([O:27][CH3:28])[c:24]([CH3:26])[cH:25]1)[CH:21]=[C:20]1[CH:15]2[CH2:16][CH2:17][CH2:18][CH2:19]1.[CH3:1][CH2:2][CH2:3][CH2:4][CH2:5][CH3:6].[CH3:45][CH2:46][O:47][CH2:48][CH3:49].[Cl-:38].[NH4+:39].[O:40]1[CH2:41][CH2:42][CH2:43][CH2:44]1>>[CH3:12][c:13]1[c:14]2[c:22]([c:23]([O:27][CH3:28])[c:24]([CH3:26])[cH:25]1)[CH:21]([CH2:33][CH:32]([O:31][CH2:29][CH3:30])[O:35][CH2:36][CH3:37])[C:20]1=[C:15]2[CH2:16][CH2:17][CH2:18][CH2:19]1

Participants

9

Reactant 8

HCID 223AmmoniumHCID 312ChlorideHCID 3283Diethyl EtherHCID 8028TetrahydrofuranHCID 8058HexaneHCID 74852Ethane, 2-bromo-1,1-diethoxy-HCID 151571995,7-dimethyl-8-methoxy-2,3,4,4a-tetrahydro-1H-fluoreneHCID 178418339Butyllithium

Product 1

HCID 151572005,7-dimethyl-8-methoxy-9-(2,2-diethoxyethyl)-1,2,3,4-tetrahydro-9H-fluorene

Sources & evidence

ORD record
ord-b468cf484a32454982af557e1f10804f
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (8/10)

Reaction notes

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