Triethylamine → [4-(1-Benzyloxycyclopropyl)phenylethynyl]-trimethylsilane

HRID 308708Notes

Reaction equation

[Br:1][c:2]1[cH:3][cH:4][c:5]([C:8]2([O:11][CH2:12][c:13]3[cH:14][cH:15][cH:16][cH:17][cH:18]3)[CH2:9][CH2:10]2)[cH:6][cH:7]1.[CH3:19][Si:20]([CH3:21])([CH3:22])[C:23]#[CH:24].[CH3:25][CH2:26][N:27]([CH2:28][CH3:29])[CH2:30][CH3:31].[Cu:32][I:33]>>[c:2]1([C:24]#[C:23][Si:20]([CH3:19])([CH3:21])[CH3:22])[cH:3][cH:4][c:5]([C:8]2([O:11][CH2:12][c:13]3[cH:14][cH:15][cH:16][cH:17][cH:18]3)[CH2:9][CH2:10]2)[cH:6][cH:7]1

Participants

Reactant 4

HCID 8471Triethylamine

HCID 24350Copper(1+) iodide; Copper(I) iodide; Cuprous iodide; Cuprous iodide (CuI)

HCID 66111Trimethylsilylacetylene

HCID 225688021-Bromo-4-(1-benzyloxycyclopropyl)benzene

Product 1

HCID 22568904[4-(1-Benzyloxycyclopropyl)phenylethynyl]-trimethylsilane

Sources & evidence

ORD record: ord-69d50ebfef244c3395cd0def26202f41
Source dataset: Training data from https://doi.org/10.1039/C8SC04228D (8/10)
DOI: 10.1039/C8SC04228D

Reaction notes

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