Dimethylformamide → HCID 67004283, compound

HRID 317863Notes

Reaction equation

HRID 317863 reaction equation
[C:19](#[CH:20])[c:21]1[cH:22][cH:23][c:24]([B:27]([OH:28])[OH:29])[cH:25][cH:26]1.[CH3:30][CH2:31][N:32]([CH2:33][CH3:34])[CH2:35][CH3:36].[Cu:42][I:43].[I:1][c:2]1[cH:3][n:4][c:5]([CH:7]2[N:8]([C:12](=[O:13])[O:14][C:15]([CH3:16])([CH3:17])[CH3:18])[CH2:9][CH2:10][CH2:11]2)[nH:6]1.[O:37]=[CH:38][N:39]([CH3:40])[CH3:41].[cH:44]1[cH:45][cH:46][c:47]([P:48]([Pd:49]([P:50]([c:51]2[cH:52][cH:53][cH:54][cH:55][cH:56]2)([c:57]2[cH:58][cH:59][cH:60][cH:61][cH:62]2)[c:63]2[cH:64][cH:65][cH:66][cH:67][cH:68]2)([P:69]([c:70]2[cH:71][cH:72][cH:73][cH:74][cH:75]2)([c:76]2[cH:77][cH:78][cH:79][cH:80][cH:81]2)[c:82]2[cH:83][cH:84][cH:85][cH:86][cH:87]2)[P:88]([c:89]2[cH:90][cH:91][cH:92][cH:93][cH:94]2)([c:95]2[cH:96][cH:97][cH:98][cH:99][cH:100]2)[c:101]2[cH:102][cH:103][cH:104][cH:105][cH:106]2)([c:107]2[cH:108][cH:109][cH:110][cH:111][cH:112]2)[c:113]2[cH:114][cH:115][cH:116][cH:117][cH:118]2)[cH:119][cH:120]1>>[c:2]1([C:20]#[C:19][c:21]2[cH:22][cH:23][c:24]([B:27]([OH:28])[OH:29])[cH:25][cH:26]2)[cH:3][n:4][c:5]([CH:7]2[N:8]([C:12](=[O:13])[O:14][C:15]([CH3:16])([CH3:17])[CH3:18])[CH2:9][CH2:10][CH2:11]2)[nH:6]1

Participants

7

Reactant 6

HCID 6228DimethylformamideHCID 8471TriethylamineHCID 24350Copper(1+) iodide; Copper(I) iodide; Cuprous iodide; Cuprous iodide (CuI)HCID 23436919(4-Ethynylphenyl)boronic acidHCID 58501743HCID 58501743, compoundHCID 178420554HCID 178420554, compound

Product 1

HCID 67004283HCID 67004283, compound

Sources & evidence

ORD record
ord-3218d7b9d10048eca9247e3bfd6e168b
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (8/10)

Reaction notes

Loading…