Azobisisobutyronitrile → HCID 86743295, compound

HRID 345916Notes

Reaction equation

HRID 345916 reaction equation
[C:1]1(=[O:7])[NH:5][C:4](=[O:6])[CH:3]=[CH:2]1.[C:8](#[N:12])[C:9]([CH3:11])=[CH2:10].CC(N=NC(C#N)(C)C)(C#N)C.C(S)CCCCCCCCCCC>CN(C=O)C>[C:4]1(=[O:6])[NH:5][C:1](=[O:7])[CH:2]=[CH:3]1.[C:8](#[N:12])[C:9]([CH3:11])=[CH2:10]

Participants

6

Reactant 4

HCID 6547AzobisisobutyronitrileHCID 81951-DodecanethiolHCID 10935MaleimideHCID 31368Methacrylonitrile

Product 1

HCID 86743295HCID 86743295, compound

Reagents, catalysts & solvents 1

HCID 6228DimethylformamideSolvent

Conditions

Temperature
90 °C

Procedure

In accordance with the procedure of Example 4, 12 g of maleimide 8.3 g of methacrylonitrile (Aldrich) 21 mL of DMF, 0.8 g of AIBN and 0.1 g of dodecanethiol were charged to a reaction vessel. The reaction mixture was heated for 15 hours at 90° C. The resultant solution was treated in accordance with procedure of Example 4. The final product (yield, 46% of theory) was dried in vacuum, overnight. The relative viscosity of the polymer, ηrel, was 1.07 (0.5 g of polymer per deciliter in dimethylformamide at 25° C.).

Workup

  1. dry with materialThe final product (yield, 46% of theory) was dried in vacuum, overnight
  2. custom1.07 (0.5 g of polymer per deciliter in dimethylformamide at 25° C.)

Sources & evidence

ORD record
ord-1dc434c05ffd4a13b267619e57ed556e
Source dataset
uspto-grants-1991_10
Patent number
US05059513

Reaction notes

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