HRID34958

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID6397

Chlorotrimethylsilane

C3H9ClSi

HCID2724682

2-Propanamine, N-(1-methylethyl)-, lithium salt

C6H14LiN

HCID14276512

未命名化合物

PRODUCTS

生成物

结构：COC(=O)c1ccc(OC)c([Si](C)(C)C)c1OC(C)C

HCID14276513

Methyl 4-methoxy-2-(1-methylethoxy)-3-(trimethylsilyl)benzoate

C15H24O4Si

AUXILIARIES

试剂、催化剂与溶剂

溶剂HCID8028

Tetrahydrofuran

C4H8O

PROCEDURE

实验过程

More specifically, Scheme 3 shows compound of the formula 9 is prepared by adding a mixture methyl 4-methoxy-2-(l-methylethoxy)benzoate of the formula (10) and chlorotrimethylsilane to a -70° C. -78° C. tetrahydrofuran solution of lithium diisopropylamide to give methyl 4-methoxy-2-(1-methylethoxy)-3-(trimethylsilyl)benzoate (11) regioselectively.

WORKUP

后处理

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