Sodium Bicarbonate → HCID 87998042, compound

HRID 352717Notes

Reaction equation

HRID 352717 reaction equation
C1(C)C=CC(S(O)(=O)=O)=CC=1.[NH2:12][C@H:13]([C:34]([O:36][CH2:37][CH2:38][C:39]([F:51])([F:50])[C:40]([F:49])([F:48])[C:41]([F:47])([F:46])[C:42]([F:45])([F:44])[F:43])=[O:35])[CH2:14][CH2:15][C:16]([O:18][CH2:19][CH2:20][C:21]([F:33])([F:32])[C:22]([F:31])([F:30])[C:23]([F:29])([F:28])[C:24]([F:27])([F:26])[F:25])=[O:17].C(=O)([O-])O.[Na+]>C(OCC)(=O)C>[NH2:12][C@H:13]([C:34]([O:36][CH2:37][CH2:38][C:39]([F:50])([F:51])[C:40]([F:48])([F:49])[C:41]([F:46])([F:47])[C:42]([F:43])([F:44])[F:45])=[O:35])[CH2:14][CH2:15][C:16]([O:18][CH2:19][CH2:20][C:21]([F:32])([F:33])[C:22]([F:30])([F:31])[C:23]([F:29])([F:28])[C:24]([F:27])([F:26])[F:25])=[O:17]

Participants

4

Reactant 2

HCID 516892Sodium BicarbonateHCID 87998041HCID 87998041, compound

Product 1

HCID 87998042HCID 87998042, compoundYield 122.2%

Reagents, catalysts & solvents 1

HCID 8857Ethyl AcetateSolvent

Procedure

In an amount of 15.0 g (19.2 mmol) of 1,5-di(3,3,4,4,5,5,6,6,6-nonafluorohexyl) glutamate p-toluenesulfonic acid salt and ethyl acetate were added with a saturated aqueous sodium hydrogencarbonate solution to wash the organic phase. Then, the organic layer was collected, and the organic solvent was evaporated under reduced pressure to obtain 15.0 g (yield: 74%) of the target compound as a yellow oily compound.

Workup

  1. washto wash the organic phase
  2. customThen, the organic layer was collected
  3. customthe organic solvent was evaporated under reduced pressure

Sources & evidence

ORD record
ord-b837a43730fc4aafbf5bc47ec721548a
Source dataset
uspto-grants-2004_06
Patent number
US06747169B2

Reaction notes

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