1,2-Epoxybutane → HCID 19601723, compound

HRID 355557Notes

Reaction equation

HRID 355557 reaction equation
[Cl:1][C:2]1[CH:3]=[C:4]([OH:8])[CH:5]=[CH:6][CH:7]=1.[CH3:9][CH2:10][CH:11]1[O:13][CH2:12]1.O.[OH-].[Li+]>>[Cl:1][C:2]1[CH:3]=[C:4]([CH:5]=[CH:6][CH:7]=1)[O:8][CH2:12][CH:11]([OH:13])[CH2:10][CH3:9]

Participants

4

Reactant 3

HCID 78341,2-EpoxybutaneHCID 79333-ChlorophenolHCID 168937Lithium hydroxide, monohydrate

Product 1

HCID 19601723HCID 19601723, compound

Procedure

is obtained analogously to Example H1 by using 51.4 g of 3-chlorophenol, 28.8 g of α-butylene oxide and 1.0 g of lithium hydroxide monohydrate in a yield of 71.4 g in the form of an oil; b.p. 83°-84° C./0.04 torr.

Sources & evidence

ORD record
ord-8628f80fa53c41af81af45fa7340732b
Source dataset
uspto-grants-1998_11
Patent number
US05831114

Reaction notes

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