1-Octene → Biphenyl

HRID 357936Notes

Reaction equation

HRID 357936 reaction equation
C=CCCCCCC.O=S(=O)(Oc1ccccc1)C(F)(F)F>CC(C)(C)[PH+](C(C)(C)C)C(C)(C)C.F[B-](F)(F)F.CCN(CC)CC.Cc1ccccc1.O=C(/C=C/c1ccccc1)/C=C/c1ccccc1.O=C(/C=C/c1ccccc1)/C=C/c1ccccc1.O=C(/C=C/c1ccccc1)/C=C/c1ccccc1.[Pd].[Pd]>c1ccc(-c2ccccc2)cc1.COc1cc(OC)cc(OC)c1.CCCCCC/C=C/c1ccccc1.C=C(CCCCCC)c1ccccc1

Participants

10

Reactant 2

HCID 81251-OcteneHCID 548641Phenyl Trifluoromethanesulfonate

Product 4

HCID 7095BiphenylHCID 693011,3,5-TrimethoxybenzeneHCID 5369452HCID 5369452, compoundHCID 12396457(Oct-1-en-2-yl)benzene

Reagents, catalysts & solvents 4

HCID 8471TriethylamineReagentHCID 2734635Tri-tert-butylphosphine tetrafluoroborateCatalystHCID 1140TolueneSolventHCID 9811564Bis(dibenzylideneacetone)palladiumOther

Conditions

Temperature
85 °C

Workup

  1. additionKeep Filtrate

Sources & evidence

ORD record
ord-a6192446663347fca13249064f1b8ee4
Source dataset
1-octene Mizoroki-Heck

Reaction notes

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