1-Octene → Biphenyl

HRID 357950Notes

Reaction equation

HRID 357950 reaction equation
C=CCCCCCC.Ic1ccccc1>Cc1cc(C)c(-n2cc[n+](-c3c(C)cc(C)cc3C)c2)c(C)c1.[Cl-].CC(C)(C)[O-].[K+].CCN(CC)CC.Cc1ccccc1.O=C(/C=C/c1ccccc1)/C=C/c1ccccc1.O=C(/C=C/c1ccccc1)/C=C/c1ccccc1.O=C(/C=C/c1ccccc1)/C=C/c1ccccc1.[Pd].[Pd]>c1ccc(-c2ccccc2)cc1.COc1cc(OC)cc(OC)c1.CCCCCC/C=C/c1ccccc1.C=C(CCCCCC)c1ccccc1

Participants

11

Reactant 2

HCID 81251-OcteneHCID 11575Iodobenzene

Product 4

HCID 7095BiphenylHCID 693011,3,5-TrimethoxybenzeneHCID 5369452HCID 5369452, compoundHCID 12396457(Oct-1-en-2-yl)benzene

Reagents, catalysts & solvents 5

HCID 8471TriethylamineReagentHCID 27342111,3-Bis(2,4,6-trimethylphenyl)imidazolium chlorideCatalystHCID 23665647Potassium tert-butoxideCatalystHCID 1140TolueneSolventHCID 9811564Bis(dibenzylideneacetone)palladiumOther

Conditions

Temperature
85 °C

Workup

  1. additionKeep Filtrate

Sources & evidence

ORD record
ord-dd8f0f19ec614b3181e2cbebd642dcf3
Source dataset
1-octene Mizoroki-Heck

Reaction notes

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