Benzoic Acid → HCID 9884634, compound
Reaction equation
[C:1]([OH:9])(=[O:8])[C:2]1[CH:7]=CC=C[CH:3]=1.[C:10]([O:15][C:16]1[CH:21]=[CH:20][C:19]([Cl:22])=[CH:18][CH:17]=1)(=O)[C:11]([CH3:13])=C.Cl[C:24]1[CH:29]=[CH:28][C:27]([OH:30])=[CH:26][CH:25]=1>>[C:1]([O:9][CH:11]([CH2:13][O:30][C:27]1[CH:28]=[CH:29][CH:24]=[CH:25][CH:26]=1)[CH2:10][O:15][C:16]1[CH:17]=[CH:18][C:19]([Cl:22])=[CH:20][CH:21]=1)(=[O:8])[C:2]([CH3:7])=[CH2:3]Participants
4
Procedure
A reaction was conducted as described in Example 6 except that benzoic acid was replaced with the same molar amount of 4-chlorophenyl methacrylate, a compound represented by formula (3) where R2 is isopropenyl and OZ1 is an organic group derived from 4-chlorophenol. Desired 1-(4-chlorophenoxy)-3-phenoxy-2-propyl methacrylate was formed in an analytical yield of 96% and isolated in a yield of 90%.
Sources & evidence
- ORD record
- ord-9ecd4b4702e24ace818b439cba42de76
- Source dataset
- uspto-grants-2000_10
- Patent number
- US06130346
Reaction notes
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