Triethylamine → 4-Ethyl-N-methoxy-2,6-dinitroaniline

HRID 371689Notes

Reaction equation

HRID 371689 reaction equation
[N+:1]([C:4]1[CH:9]=[C:8]([CH3:10])[CH:7]=[C:6]([N+:11]([O-:13])=[O:12])[C:5]=1Cl)([O-:3])=[O:2].Cl.[CH3:16][O:17][NH2:18].[CH2:19](N(CC)CC)C>>[N+:1]([C:4]1[CH:9]=[C:8]([CH2:10][CH3:19])[CH:7]=[C:6]([N+:11]([O-:13])=[O:12])[C:5]=1[NH:18][O:17][CH3:16])([O-:3])=[O:2]

Participants

4

Reactant 3

HCID 8471TriethylamineHCID 789184-Chloro-3,5-dinitrotolueneHCID 521874O-Methylhydroxylamine hydrochloride

Product 1

HCID 213298884-Ethyl-N-methoxy-2,6-dinitroaniline

Procedure

Following the same general procedure of Example 2 and using 21.6 g. (0.1 mole) of 2,6-dinitro-4-methylchlorobenzene, 12.5 g. (0.15 mole) of methoxyamine hydrochloride, and 25.25 g. (0.25 mole) of triethylamine, the following additional compound was prepared:

Sources & evidence

ORD record
ord-e0058999847d4b7e9fc115ed115fe4bb
Source dataset
uspto-grants-1978_05
Patent number
US04087460

Reaction notes

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