Hydrochloric Acid → N-Methyl-N(4-t-Butylphenylthiosulfenyl) Carbamoyl Fluoride

HRID 372375Notes

Reaction equation

HRID 372375 reaction equation
[C:1]([C:5]1[CH:10]=[CH:9][C:8]([SH:11])=[CH:7][CH:6]=1)([CH3:4])([CH3:3])[CH3:2].CN(Cl)C(F)=S.Cl.[CH3:19][N:20]([S:24]SC1C=CC(Cl)=CC=1)[C:21]([F:23])=[O:22]>CCCCC>[CH3:19][N:20]([S:24][S:11][C:8]1[CH:7]=[CH:6][C:5]([C:1]([CH3:4])([CH3:2])[CH3:3])=[CH:10][CH:9]=1)[C:21]([F:23])=[O:22]

Participants

6

Reactant 4

HCID 313Hydrochloric AcidHCID 754544-Tert-ButylbenzenethiolHCID 20327306N-methyl-N-chlorothiocarbamoyl fluorideHCID 23333002N-methyl-N-(4-chlorophenylthiosulfenyl)carbamoyl fluoride

Product 1

HCID 23333006N-Methyl-N(4-t-Butylphenylthiosulfenyl) Carbamoyl Fluoride

Reagents, catalysts & solvents 1

HCID 8003PentaneSolvent

Procedure

Prepared by reacting 0.5 g of 4-t-butylthiophenol in pentane with 0.44 g of N-methyl-N-chlorothiocarbamoyl fluoride. The reaction proceded with a vigorous exotherm and evolution of hydrochloric acid gas. The infrared and n.m.r. spectra of the product was identical to the material prepared by Method I.

Workup

  1. customPrepared

Sources & evidence

ORD record
ord-fa71a60d6f244171a56e63b8bc36ee36
Source dataset
uspto-grants-1978_05
Patent number
US04091016

Reaction notes

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