Methane → HCID 53899950, compound

HRID 372863Notes

Reaction equation

HRID 372863 reaction equation
Br[CH:2]([CH2:22][C:23]([Cl:26])([Cl:25])[Cl:24])[CH2:3][CH2:4][C:5]([O:7][CH2:8][C:9]1[CH:14]=[CH:13][CH:12]=[C:11]([O:15][C:16]2[CH:21]=[CH:20][CH:19]=[CH:18][CH:17]=2)[CH:10]=1)=[O:6].N1CCCC[CH2:28]1.[CH4:33]>C1C=CC=CC=1>[CH3:33][C:3]([CH3:28])([CH:2]=[CH:22][C:23]([Cl:26])([Cl:25])[Cl:24])[CH2:4][C:5]([O:7][CH2:8][C:9]1[CH:14]=[CH:13][CH:12]=[C:11]([O:15][C:16]2[CH:21]=[CH:20][CH:19]=[CH:18][CH:17]=2)[CH:10]=1)=[O:6]

Participants

5

Reactant 3

HCID 297MethaneHCID 8082PiperidineHCID 20327149HCID 20327149, compound

Product 1

HCID 53899950HCID 53899950, compound

Reagents, catalysts & solvents 1

HCID 241BenzeneSolvent

Procedure

In the manner of Example II, 22.1 g of 3-phenoxybenzyl 4-bromo-6,6,6-trichlorohexanoate was treated with 7.4 g of piperidine. Chromatography of the crude reaction product on a charcoal column using benzene as the eluent gave 13.5 g of 3-phenoxybenzyl 3,3-dimethyl-6,6,6-trichloro-4-hexenoate.

Sources & evidence

ORD record
ord-81b9c944d55345e6998fbc7e629942ca
Source dataset
uspto-grants-1978_05
Patent number
US04092482

Reaction notes

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