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HRID375683

反应详情

EQUATION

反应方程式

HRID 375683 的结构方程式

REACTANTS

反应物

4
结构：O
HCID962

Water

H2O

结构：C1CCNCC1
HCID8082

Piperidine

C5H11N

结构：COC(OC)N(C)C
HCID78373

Methanamine, 1,1-dimethoxy-N,N-dimethyl-

C5H13NO2

结构：COC(=O)c1cccc(C)c1[N+](=O)[O-]
HCID79621

Benzoic acid, 3-methyl-2-nitro-, methyl ester

C9H9NO4

PRODUCTS

生成物

1
结构：N#CCCc1cccc2cc[nH]c12
HCID19959105

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

1
结构：CN(C)C=O
溶剂HCID6228

N,N-Dimethylformamide

C3H7NO

PROCEDURE

实验过程

A solution of methyl 3-methyl-2-nitrobenzoate (43 g, 0.22 mole), dimethylformamide dimethyl acetal (52.5 g, 0.44 mole) and piperidine (18.7 g, 0.22 mole) in dimethylformamide (120 ml) is heated under reflux for 24 hours, cooled and poured into water to give the crude product.

WORKUP

后处理

  1. temperatureunder reflux for 24 hours
  2. temperaturecooled