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HRID376867

反应详情

EQUATION

反应方程式

HRID 376867 的结构方程式

REACTANTS

反应物

5
结构：N=C(N)N
HCID3520

Guanidine

CH5N3

结构：CS(=O)(=O)c1cc(C(=O)O)ccc1Cl
HCID182670

4-Chloro-3-(methanesulfonyl)benzoato

C8H7ClO4S

结构：Cc1ccc(O[Si](C)(C)C)cn1
HCID597272

未命名化合物

结构：COC(=O)c1ccc(Oc2ccc(C)nc2)c(S(C)(=O)=O)c1
HCID19360282

未命名化合物

结构：CI.O=C([O-])[O-].[K+].[K+]
HCID86747754

未命名化合物

PRODUCTS

生成物

1
结构：Cc1ccc(Oc2ccc(C(=O)N=C(N)N)cc2S(C)(=O)=O)cn1
HCID19360327

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

1
结构：CN(C)C=O
溶剂HCID6228

N,N-Dimethylformamide

C3H7NO

PROCEDURE

实验过程

In analogy with Example 2, reacting guanidine with methyl 3-methylsulfonyl-4-(6-methyl-3-pyridyloxy)benzoate [obtainable by reacting 3-methylsulfonyl-4-chlorobenzoic acid with 6-methyl-3-trimethylsilyloxypyridine and subsequently esterifying the product with methyl iodide/K2CO3 in DMF] gives N-diaminomethylene-3-methylsulfonyl-4-(6-methyl-3-pyridyloxy)benzamide, m.p. 197-199°.