1,4-Dichlorobenzene → HCID 14298267, compound

HRID 389238Notes

Reaction equation

HRID 389238 reaction equation
[CH3:1][C:2]1[S:3][C:4]2[CH:10]=[C:9]([N+:11]([O-:13])=[O:12])[CH:8]=[CH:7][C:5]=2[N:6]=1.[CH2:14]([I:16])[CH3:15].C1C(Cl)=CC=C(Cl)C=1>C(OCC)(=O)C>[I-:16].[CH2:14]([N+:6]1[C:5]2[CH:7]=[CH:8][C:9]([N+:11]([O-:13])=[O:12])=[CH:10][C:4]=2[S:3][C:2]=1[CH3:1])[CH3:15]

Participants

5

Reactant 3

HCID 46851,4-DichlorobenzeneHCID 6340IodoethaneHCID 76250Benzothiazole, 2-methyl-6-nitro-

Product 1

HCID 14298267HCID 14298267, compound

Reagents, catalysts & solvents 1

HCID 8857Ethyl AcetateSolvent

Conditions

Temperature
120 °C

Procedure

To 2-methyl-6-nitrobenzothiazole (0.36 g) was added ethyl iodide (1.5 ml) and dichlorobenzene (20 ml). The mixture was heated to 120° C. for 2 days and then allowed to cool to room temperature. Ethyl acetate was added and the resulting precipitate removed by filtration. Drying in a vacuum oven gave the desired material (80 mg).

Workup

  1. temperatureto cool to room temperature
  2. customthe resulting precipitate removed by filtration
  3. customDrying in a vacuum oven

Sources & evidence

ORD record
ord-96c1b9790d6748e79d838e18df049e74
Source dataset
uspto-grants-2013_02
Patent number
US08378120B2

Reaction notes

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