4-tert-Butylcyclohexanone → HCID 53974670, compound

HRID 412504Notes

Reaction equation

HRID 412504 reaction equation
[C:1]([CH:5]1[CH2:10]C[C:8](=O)[CH2:7][CH2:6]1)([CH3:4])([CH3:3])[CH3:2].ClC1C=C(C=CC=1)C(OO)=O.[C:23](=[O:26])(O)[O-:24].[Na+]>ClCCl>[C:1]([CH:5]1[CH2:10][O:24][C:23](=[O:26])[CH2:8][CH2:7][CH2:6]1)([CH3:4])([CH3:3])[CH3:2]

Participants

5

Reactant 3

HCID 73924-tert-ButylcyclohexanoneHCID 70297m-Chloroperbenzoic acidHCID 516892Sodium Bicarbonate

Product 1

HCID 53974670HCID 53974670, compound

Reagents, catalysts & solvents 1

HCID 6344DichloromethaneSolvent

Procedure

This was prepared in the same manner as Lactone 1 except using 4-tert butylcyclohexanone (10 parts, 0.065 m ex. Aldrich), 3-chloroperoxybenzoic acid (17.5 parts, 0.0713M), sodium bicarbonate (11.5 parts, 0.143M) and dichloromethane (750 ml) in place of the 3-methyl cyclohexanone and amounts described for Lactone 1. The product was obtained as an oil (10.2 parts).

Workup

  1. customThe product was obtained as an oil (10.2 parts)

Sources & evidence

ORD record
ord-d5c2586ee21b41b29270bac94bacbffb
Source dataset
uspto-grants-2003_05
Patent number
US06562897B1

Reaction notes

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