HRID4158

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID313

Hydrochloric Acid

ClH

HCID7954

2,4,6-Trichloro-s-triazine

C3Cl3N3

HCID4446056

未命名化合物

PRODUCTS

生成物

结构：CCCCCCCCCCOC(=O)c1ccc(NN2CN(Nc3ccc(C(=O)OCCCCCCCCCC)cc3)CN(Nc3ccc(C(=O)OCCCCCCCCCC)cc3)C2)cc1

HCID20152734

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

溶剂HCID7237

o-Xylene

C8H10

CONDITIONS

反应条件

温度: 90 °C

PROCEDURE

实验过程

83 g of decyl p-aminobenzoate and 18.5 g of cyanuric chloride in 1,000 ml of xylene were heated at 140° C. for 8 hours. After the evolution of hydrogen chloride was complete, the reaction solution was cooled to 90° C., washed twice with saturated sodium bicarbonate solution and once with water, and then cooled to room temperature. The white crystals precipitated were filtered off under suction and dried.

WORKUP

后处理

washwashed twice with saturated sodium bicarbonate solution and once with water
temperaturecooled to room temperature
customThe white crystals precipitated
filtrationwere filtered off under suction
customdried

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-d7ec7c5243894addb439002cd6f1f99a
来源数据集: uspto-grants-1988_02
DOI: 10.6084/m9.figshare.5104873.v1
专利: US04724137
来源说明: uspto-grants-1988_02

反应 SMILES

[NH2:1][C:2]1[CH:20]=[CH:19][C:5]([C:6]([O:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH3:18])=[O:7])=[CH:4][CH:3]=1.[N:21]1[C:28](Cl)=[N:27][C:25](Cl)=[N:24][C:22]=1Cl.Cl>C1(C)C(C)=CC=CC=1>[CH2:9]([O:8][C:6]([C:5]1[CH:4]=[CH:3][C:2]([NH:1][N:21]2[CH2:28][N:27]([NH:1][C:2]3[CH:20]=[CH:19][C:5]([C:6]([O:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH3:18])=[O:7])=[CH:4][CH:3]=3)[CH2:25][N:24]([NH:1][C:2]3[CH:3]=[CH:4][C:5]([C:6]([O:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH3:18])=[O:7])=[CH:19][CH:20]=3)[CH2:22]2)=[CH:20][CH:19]=1)=[O:7])[CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH3:18]