1,2-Dichloroethane → HCID 53740612, compound

HRID 436651Notes

Reaction equation

HRID 436651 reaction equation
[CH2:1]([NH2:9])[CH2:2][CH:3]=[CH:4][CH2:5][CH2:6][CH2:7][NH2:8].[CH2:10](Cl)[CH2:11]Cl.[C:14](=[O:17])([O-])[O-].[K+].[K+].[CH3:20][O:21][C:22]1[CH:30]=[CH:29][C:25]([C:26](Cl)=[O:27])=[CH:24][CH:23]=1>O>[CH2:1]([NH:9][C:14](=[O:17])[C:11]1[CH:10]=[CH:30][C:22]([O:21][CH3:20])=[CH:23][CH:24]=1)[CH2:2][CH:3]=[CH:4][CH2:5][CH2:6][CH2:7][NH:8][C:26](=[O:27])[C:25]1[CH:29]=[CH:30][C:22]([O:21][CH3:20])=[CH:23][CH:24]=1

Participants

6

Reactant 4

HCID 111,2-DichloroethaneHCID 7477p-Anisoyl chlorideHCID 11430Potassium CarbonateHCID 53866113Hept-3-ene-1,7-diamine

Product 1

HCID 53740612HCID 53740612, compound

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Procedure

m.p. 141°-143° C., 10.2 g., was prepared as in Example 21 using 8.37 g. of 3-heptene-1,7-diamine, 50 ml. of ethylene dichloride, 18.0 g. of potassium carbonate, 100 ml. of water, 22.4 g. of 4-methoxybenzoyl chloride in 50 ml. ethylene dichloride and recrystallization from methanol.

Workup

  1. custom, was prepared as in Example 21 using 8.37 g
  2. customethylene dichloride and recrystallization from methanol

Sources & evidence

ORD record
ord-37cddb9afff44fe0866106b8d0f35054
Source dataset
uspto-grants-1977_02
Patent number
US04009208

Reaction notes

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