2,4-Dichlorophenol → HCID 54431477, compound

HRID 443610Notes

Reaction equation

HRID 443610 reaction equation
[Cl:1][C:2]1[CH:7]=[C:6]([Cl:8])[CH:5]=[CH:4][C:3]=1[OH:9].[Cl:10][CH2:11][C:12]1[CH:20]=[CH:19][C:15]([C:16](Cl)=[O:17])=[CH:14][CH:13]=1.CN1CCCC1>C1(C)C(C)=CC=CC=1>[Cl:1][C:2]1[CH:7]=[C:6]([Cl:8])[CH:5]=[CH:4][C:3]=1[O:9][C:16](=[O:17])[C:15]1[CH:19]=[CH:20][C:12]([CH2:11][Cl:10])=[CH:13][CH:14]=1

Participants

5

Reactant 3

HCID 84492,4-DichlorophenolHCID 84541-MethylpyrrolidineHCID 701364-(Chloromethyl)benzoyl chloride

Product 1

HCID 54431477HCID 54431477, compound

Reagents, catalysts & solvents 1

HCID 7237O-XyleneSolvent2×

Procedure

81.5 g (0.5 mole) of 2,4-dichlorophenol was dissolved in 100 ml of absolute xylene, mixed with a solution of 95 g (0.5 mole) of p-chloromethylbenzoyl chloride in 80 ml of xylene, and after the addition of 0.5 ml of N-methylpyrrolidine the mixture was refluxed for 6 to 7 hours in a weak current of nitrogen.

Workup

  1. temperaturewas refluxed for 6 to 7 hours in a weak current of nitrogen

Sources & evidence

ORD record
ord-a4f4af55c2f9476c8d33088debd909b4
Source dataset
uspto-grants-1981_04
Patent number
US04260803

Reaction notes

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