Thioanisole → HCID 178506884, compound

HRID 462307Notes

Reaction equation

HRID 462307 reaction equation
[C:1]1([S:7][CH3:8])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.C([Li:13])CCC>CCCCCC.O1CCCC1>[C:1]1([S:7][CH2:8][Li:13])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1

Participants

5

Reactant 2

HCID 7520ThioanisoleHCID 178418339Butyllithium

Product 1

HCID 178506884HCID 178506884, compound

Reagents, catalysts & solvents 2

HCID 8028TetrahydrofuranSolvent2×HCID 8058HexaneSolvent

Procedure

To a solution of 1.17 ml. of thioanisole in 20 ml. of dry tetrahydrofuran were added 8.4 ml. of a 1.2M solution of n-butyllithium in n-hexane at -20° C. and the mixture was stirred at the same temperature of 1.5 hours to give a 0.28M solution of phenylthiomethyllithium in tetrahydrofuran.

Sources & evidence

ORD record
ord-a2b84e137900498fa3034aa88ad675d5
Source dataset
uspto-grants-1977_12
Patent number
US04065632

Reaction notes

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