Triethylamine → HCID 20397540, compound

HRID 462842Notes

Reaction equation

HRID 462842 reaction equation
Cl[CH2:2][CH2:3][S:4]([CH2:7][CH2:8][C:9]([F:27])([F:26])[C:10]([F:25])([F:24])[C:11]([F:23])([F:22])[C:12]([F:21])([F:20])[C:13]([F:19])([F:18])[C:14]([F:17])([F:16])[F:15])(=[O:6])=[O:5].C(N(CC)CC)C>C1COCC1>[CH:3]([S:4]([CH2:7][CH2:8][C:9]([F:27])([F:26])[C:10]([F:24])([F:25])[C:11]([F:22])([F:23])[C:12]([F:20])([F:21])[C:13]([F:18])([F:19])[C:14]([F:15])([F:16])[F:17])(=[O:6])=[O:5])=[CH2:2]

Participants

4

Reactant 2

HCID 8471TriethylamineHCID 203975378-(2-Chloroethanesulfonyl)-1,1,1,2,2,3,3,4,4,5,5,6,6-tridecafluorooctane

Product 1

HCID 20397540HCID 20397540, compound

Reagents, catalysts & solvents 1

HCID 8028TetrahydrofuranSolvent2×

Procedure

2-(Perfluorohexyl)ethanyl 2-chloroethanyl sulfone (4.75 g, 10.0 mmole) was dissolved in 25 ml of THF at 30°, and triethylamine (1.52 g, 15.0 mmole) in 10 ml of THF was added in one minute. A white precipitate formed, and was filtered (1.37 g). The solvent was stripped carefully, as some foaming occurred.

Workup

  1. customA white precipitate formed
  2. filtrationwas filtered (1.37 g)

Sources & evidence

ORD record
ord-c3683595c59f405c8c1c64c3c3bb343a
Source dataset
uspto-grants-1985_05
Patent number
US04517384

Reaction notes

Loading…