Azobisisobutyronitrile → HCID 86587193, compound

HRID 480530Notes

Reaction equation

HRID 480530 reaction equation
[CH3:1][N:2]1[C:6](=[O:7])[CH:5]=[CH:4][C:3]1=[O:8].[F:9][CH:10]([CH2:24][C:25]([F:28])([F:27])[F:26])[C:11]([O:14][C:15]([CH:17]1[CH2:22][CH:21]2[CH2:23][CH:18]1[CH:19]=[CH:20]2)=[O:16])([F:13])[F:12].[F:29][CH:30]1[CH:41]=[CH:40][CH:39]=[C:38]([F:42])[C:31]1([CH3:43])[CH2:32]C(=C)C([O-])=O.CC(N=NC(C#N)(C)C)(C#N)C>O1CCCC1>[CH3:1][N:2]1[C:6](=[O:7])[CH:5]=[CH:4][C:3]1=[O:8].[F:9][CH:10]([CH2:24][C:25]([F:26])([F:27])[F:28])[C:11]([O:14][C:15]([CH:17]1[CH2:22][CH:21]2[CH2:23][CH:18]1[CH:19]=[CH:20]2)=[O:16])([F:13])[F:12].[F:42][CH:38]1[CH:39]=[CH:40][CH:41]=[C:30]([F:29])[C:31]1([CH3:43])[CH2:32][C:18]12[CH2:23][CH:21]([CH:20]=[CH:19]1)[CH2:22][CH:17]2[C:15]([O-:14])=[O:16]

Participants

6

Reactant 4

HCID 6547AzobisisobutyronitrileHCID 70261N-MethylmaleimideHCID 86587194HCID 86587194, compoundHCID 86587195HCID 86587195, compound

Product 1

HCID 86587193HCID 86587193, compound

Reagents, catalysts & solvents 1

HCID 8028TetrahydrofuranSolvent

Procedure

To 20 mL of tetrahydrofuran was added 50 mmole of N-methylmaleimide, 10 mmole of hexafluorobutyl-5-norbornene-2-carboxylate, 40 mmole of 2,6-difluoro-1-methylbenzylacrylate and 0.3 g of AIBN, and the resulting solution was reacted at about 65° C. for about 12 hours.

Workup

  1. customthe resulting solution was reacted at about 65° C. for about 12 hours

Sources & evidence

ORD record
ord-94a78c7e2a854180a897ba4f24b78a41
Source dataset
uspto-grants-2003_11
Patent number
US06653047B2

Reaction notes

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