Butyl iodide → HCID 19750825, compound

HRID 484108Notes

Reaction equation

HRID 484108 reaction equation
[CH2:1]([S:3][C:4]1[C:5]2[C:6]3[C:10](=[CH:11][CH:12]=1)[NH:9][C:8](=[O:13])[C:7]=3[CH:14]=[CH:15][CH:16]=2)C.[H-].[Na+].[CH2:19](I)[CH2:20][CH2:21][CH3:22]>>[CH2:19]([N:9]1[C:10]2[C:6]3[C:5](=[CH:16][CH:15]=[CH:14][C:7]=3[C:8]1=[O:13])[C:4]([S:3][CH3:1])=[CH:12][CH:11]=2)[CH2:20][CH2:21][CH3:22]

Participants

4

Reactant 3

HCID 10962Butyl iodideHCID 24758Sodium hydrideHCID 19750821HCID 19750821, compound

Product 1

HCID 19750825HCID 19750825, compound

Procedure

A mixture of 2.15 g of 6-(methylthio)-benz[cd]indol-2(1H)-one (Example 12), 0.6 g of 60% sodium hydride and 1.7 ml of butyl iodide in 70 ml are reacted as described in Example 16 giving 1.85 g of the desired product as a solid, m.p. 75°-77° C.

Workup

  1. customare reacted

Sources & evidence

ORD record
ord-4d7550a92b6d4073bc9b0cc39eb07d0a
Source dataset
uspto-grants-1993_07
Patent number
US05229411

Reaction notes

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