Gamma-Butyrolactone → 1-Octadecylpyrrolidin-2-one

HRID 487238Notes

Reaction equation

HRID 487238 reaction equation
[CH2:1]([NH2:19])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH3:18].C(N)CCCCCCCCCCC.[C:33]1(=O)[O:37][CH2:36][CH2:35][CH2:34]1>O>[CH2:1]([N:19]1[CH2:33][CH2:34][CH2:35][C:36]1=[O:37])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH3:18]

Participants

5

Reactant 3

HCID 7302Gamma-ButyrolactoneHCID 13583DodecylamineHCID 15793Octadecylamine

Product 1

HCID 819261-Octadecylpyrrolidin-2-oneYield 96%

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Procedure

The procedure described in Example I was repeated except that octadecylamine (Armeen 18D) was substituted for n-dodecylamine and the product was stripped of water and excess butyrolactone and was discharged at about 75° C. to provide 96% pure N-octadecyl-2-pyrrolidone solid in a yield of 96%.

Workup

  1. customwas discharged at about 75° C.

Sources & evidence

ORD record
ord-a89195aaace64e34b5b1e4776d878a07
Source dataset
uspto-grants-1994_03
Patent number
US05294644

Reaction notes

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