Diphenyl Ether → HCID 67073672, compound

HRID 493409Notes

Reaction equation

HRID 493409 reaction equation
[Al+3].[Cl-].[Cl-].[Cl-].[C:5]1([O:11][C:12]2[CH:17]=[CH:16][CH:15]=[CH:14][CH:13]=2)[CH:10]=[CH:9][CH:8]=[CH:7][CH:6]=1.[Br:18][C:19]([CH3:24])([CH3:23])[C:20](Br)=[O:21]>ClCCl>[Br:18][C:19]([CH3:24])([CH3:23])[C:20]([C:15]1[CH:14]=[CH:13][C:12]([O:11][C:5]2[CH:6]=[CH:7][CH:8]=[CH:9][CH:10]=2)=[CH:17][CH:16]=1)=[O:21]

Participants

5

Reactant 3

HCID 7583Diphenyl EtherHCID 886852-Bromo-2-methylpropionyl bromideHCID 6451240Aluminum(III) Chloride

Product 1

HCID 67073672HCID 67073672, compound

Reagents, catalysts & solvents 1

HCID 6344DichloromethaneSolvent

Procedure

7.82 g of AlCl3 were added in about 30′ to a solution of 10 g (0.0587 mol) of diphenylether and 7.44 ml (0.0587 mol) of α-bromoisobutyrylbromide (97.5% w/w) in 100 ml of dichloromethane, maintaining the temperature between 0 e 5° C.

Workup

  1. temperaturemaintaining the temperature between 0 e 5° C.

Sources & evidence

ORD record
ord-48dc9b1a463144da8421c084cb8929a9
Source dataset
uspto-grants-2009_05
Patent number
US07534880B2

Reaction notes

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