Saccharin → HCID 66664772, compound

HRID 582947Notes

Reaction equation

HRID 582947 reaction equation
[S:1]1([C:12]2[C:7](=[CH:8][CH:9]=[CH:10][CH:11]=2)[C:5](=[O:6])[NH:4]1)(=[O:3])=[O:2].OC[C@@H]([C@H]([C@@H]([C@@H](CO)O)O)O)O.C(=O)([O-])[O-].[Li+].[Li+].[Li:31]>O>[S:1]1([C:12]2[C:7](=[CH:8][CH:9]=[CH:10][CH:11]=2)[C:5](=[O:6])[NH:4]1)(=[O:2])=[O:3].[Li:31]

Participants

6

Reactant 4

HCID 5143Saccharin4×HCID 5780SorbitolHCID 11125Lithium CarbonateHCID 3028194Lithium

Product 1

HCID 66664772HCID 66664772, compound

Reagents, catalysts & solvents 1

HCID 962WaterSolvent2×

Conditions

Temperature
49 °C

Procedure

For Samples 3-6, the sorbitol, 70% was charged to a kettle, followed by the sucrose, d-maltose, and Cornsweet 95, 77%. All of these were mixed until fully dissolved to produce a sorbitol intermediate mixture. The dissolving process was hastened by the application of low heat (approximately 49° C.). The saccharin and water were charged to a second kettle and mixed. The saccharin dispersed in the water but did not dissolve because saccharin is not water soluble. Then lithium carbonate was charged to the second kettle. A foaming reaction occurred as the lithium salt of saccharin was created, and the contents of the second kettle were mixed until the product was clear, to produce a lithium saccharin intermediate mixture. The contents of the second kettle were added to the sorbitol intermediate mixture of the first kettle.

Workup

  1. additionmixed
  2. customA foaming reaction
  3. additionthe contents of the second kettle were mixed until the product

Sources & evidence

ORD record
ord-3c6ec796eeea4af8bb1666fac323b881
Source dataset
uspto-grants-1999_07
Patent number
US05928634

Reaction notes

Loading…