Methane → HCID 21847869, compound

HRID 618666Notes

Reaction equation

HRID 618666 reaction equation
[NH:1]1[C:5]2[CH:6]=[CH:7][CH:8]=[CH:9][C:4]=2[N:3]=[N:2]1.[Cl:10][C:11]([Cl:21])([O:13][C:14](=O)[O:15]C(Cl)(Cl)Cl)[Cl:12].C.C1(C)C=CC=CC=1>CCCCCC.CCOCC>[Cl:10][C:11]([O:13][C:14]([N:1]1[C:5]2[CH:6]=[CH:7][CH:8]=[CH:9][C:4]=2[N:3]=[N:2]1)=[O:15])([Cl:21])[Cl:12]

Participants

7

Reactant 4

HCID 297MethaneHCID 1140TolueneHCID 94429TriphosgeneHCID 178418385HCID 178418385, compound

Product 1

HCID 21847869HCID 21847869, compound

Reagents, catalysts & solvents 2

HCID 3283Diethyl EtherSolventHCID 8058HexaneSolvent

Procedure

A stirred mixture of benzotriazole (3 g), triphosgene (11.22 g), charcoal (1 g) and anhydrous toluene was refluxed overnight and filtered. Evaporation of the filtrate gave an oily solid which was suspended in a mixture of hexane and ether (1:1). Filtration and evaporation of the filtrate gave the titled compound as an oil.

Workup

  1. temperaturewas refluxed overnight
  2. filtrationfiltered
  3. customEvaporation of the filtrate
  4. customgave an oily solid which
  5. filtrationFiltration and evaporation of the filtrate

Sources & evidence

ORD record
ord-34e0ae09921a4e73b0bf41fef4e4e8fb
Source dataset
uspto-grants-1999_09
Patent number
US05955470

Reaction notes

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