Benzaldehyde → HCID 13806364, compound

HRID 648113Notes

Reaction equation

HRID 648113 reaction equation
[Cl-].[Cl-].[C:3]1([N:9](B)[C:10]2[CH:15]=[CH:14][CH:13]=[CH:12][CH:11]=2)[CH:8]=[CH:7][CH:6]=[CH:5][CH:4]=1.[CH:17](=[O:24])[C:18]1[CH:23]=[CH:22][CH:21]=[CH:20][CH:19]=1.C(N(CCCC)CCCC)CCC>>[C:3]1([NH:9][C:10]2[CH:15]=[CH:14][CH:13]=[CH:12][C:11]=2[CH:17]([OH:24])[C:18]2[CH:23]=[CH:22][CH:21]=[CH:20][CH:19]=2)[CH:8]=[CH:7][CH:6]=[CH:5][CH:4]=1

Participants

4

Reactant 3

HCID 240BenzaldehydeHCID 7622TributylamineHCID 178419228HCID 178419228, compound

Product 1

HCID 13806364HCID 13806364, compoundYield 22.4%

Procedure

Using diphenylaminoborane dichloride (200 mg), benzaldehyde (85 mg) and tri-n-butylamine (147 mg), the reaction is effected as in Example 7, whereby 2-phenylaminobenzhydrol (49 mg) is obtained. This substance is recrystallized from benzene-hexane to give crystals melting at 111° to 112° C. Anal. Calcd. for C19H17ON: C, 82.88; H, 6.62; N, 5.09. Found: C, 82.67; H, 6.28; N, 5.03.

Sources & evidence

ORD record
ord-ee411a5bfb7f42d18b0f0fc1e0e695e8
Source dataset
uspto-grants-1983_10
Patent number
US04410730

Reaction notes

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