Sodium Iodide → 9-(Methoxycarbonyl)-nonyl-triphenyl-phosphonium bromide

HRID 653087Notes

Reaction equation

HRID 653087 reaction equation
[CH3:1][O:2][C:3](=[O:14])[CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][Br:13].[C:15]1([P:21]([C:28]2[CH:33]=[CH:32][CH:31]=[CH:30][CH:29]=2)[C:22]2[CH:27]=[CH:26][CH:25]=[CH:24][CH:23]=2)[CH:20]=[CH:19][CH:18]=[CH:17][CH:16]=1.[I-].[Na+]>C(#N)C>[Br-:13].[CH3:1][O:2][C:3]([CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][P+:21]([C:22]1[CH:23]=[CH:24][CH:25]=[CH:26][CH:27]=1)([C:28]1[CH:33]=[CH:32][CH:31]=[CH:30][CH:29]=1)[C:15]1[CH:16]=[CH:17][CH:18]=[CH:19][CH:20]=1)=[O:14]

Participants

5

Reactant 3

HCID 5238Sodium IodideHCID 11776TriphenylphosphineHCID 554079Methyl 10-bromodecanoate

Product 1

HCID 107446959-(Methoxycarbonyl)-nonyl-triphenyl-phosphonium bromide

Reagents, catalysts & solvents 1

HCID 6342AcetonitrileSolvent

Procedure

A mixture of methyl-10bromodecanoate (5.22 g), triphenylphosphine (7.74 g) and sodium iodide (0.3 g) in acetonitrile (50 ml) was refluxed for 24 hours.

Workup

  1. temperaturewas refluxed for 24 hours

Sources & evidence

ORD record
ord-3718753e28e449c788e5d50ff67a1cd8
Source dataset
uspto-grants-1987_06
Patent number
US04675335

Reaction notes

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