Methacrylic Acid → HCID 178438938, compound

HRID 654979Notes

Reaction equation

HRID 654979 reaction equation
[C:1]([OH:6])(=O)[C:2]([CH3:4])=[CH2:3].C(N([CH2:12][CH3:13])CC)C.C1([SH:20])C=CC=CC=1.O1[CH2:25][CH2:24][CH2:23][CH2:22]1>>[CH3:3][CH:2]([CH2:4][C:13]1[CH:12]=[CH:25][CH:24]=[CH:23][CH:22]=1)[C:1]([OH:6])=[S:20]

Participants

5

Reactant 4

HCID 4093Methacrylic AcidHCID 7969ThiophenolHCID 8028TetrahydrofuranHCID 8471Triethylamine

Product 1

HCID 178438938HCID 178438938, compound

Procedure

Methacrylic acid (6.88 g; 80 mmole) was dissolved in dry tetrahydrofuran (40 ml), and triethylamine (8.0 g; 80 mmole) and thiophenol (8.81 g; 80 mmole) were successively added thereto at room temperature, followed by stirring for 24 hours. Removal of the solvent under reduced pressure gave 2-methyl-3-phenylthiopropionic acid.

Workup

  1. customat room temperature
  2. customRemoval of the solvent under reduced pressure

Sources & evidence

ORD record
ord-b4d245a210164760a316806f5c8411b9
Source dataset
uspto-grants-1992_07
Patent number
US05134231

Reaction notes

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