Styrene → 1,1-Diphenylethylene

HRID 68046Notes

Reaction equation

HRID 68046 reaction equation
C=Cc1ccccc1.Ic1ccccc1>c1ccc(P(c2ccccc2)C23C4C5C6C2[Fe]56432789C3C2C7C8(P(c2ccccc2)c2ccccc2)C39)cc1.CCN(CC)CC.Cc1ccccc1.C1=C\CC/C=C\CC/1.C1=C\CC/C=C\CC/1.[Ni]>C=C(c1ccccc1)c1ccccc1.COc1cc(OC)cc(OC)c1.C(=C\c1ccccc1)/c1ccccc1

Participants

9

Reactant 2

HCID 7501StyreneHCID 11575Iodobenzene

Product 3

HCID 107401,1-DiphenylethyleneHCID 693011,3,5-TrimethoxybenzeneHCID 638088trans-Stilbene

Reagents, catalysts & solvents 4

HCID 8471TriethylamineReagentHCID 178418185HCID 178418185, compoundCatalystHCID 1140TolueneSolventHCID 6433264Bis(1,5-cyclooctadiene)nickelOther

Conditions

Temperature
85 °C

Workup

  1. additionKeep Filtrate

Sources & evidence

ORD record
ord-14f33e924ede436686e3bb3ff049880c
Source dataset
Styrene Mizoroki-Heck

Reaction notes

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