Styrene → 1,1-Diphenylethylene

HRID 68073Notes

Reaction equation

HRID 68073 reaction equation
C=Cc1ccccc1.Ic1ccccc1>c1ccc(P(c2ccccc2)c2ccccc2)cc1.CCN(CC)CC.Cc1ccccc1.O=C(/C=C/c1ccccc1)/C=C/c1ccccc1.O=C(/C=C/c1ccccc1)/C=C/c1ccccc1.O=C(/C=C/c1ccccc1)/C=C/c1ccccc1.[Pd].[Pd]>C=C(c1ccccc1)c1ccccc1.COc1cc(OC)cc(OC)c1.C(=C\c1ccccc1)/c1ccccc1

Participants

9

Reactant 2

HCID 7501StyreneHCID 11575Iodobenzene

Product 3

HCID 107401,1-DiphenylethyleneHCID 693011,3,5-TrimethoxybenzeneHCID 638088trans-Stilbene

Reagents, catalysts & solvents 4

HCID 8471TriethylamineReagentHCID 11776TriphenylphosphineCatalystHCID 1140TolueneSolventHCID 9811564Bis(dibenzylideneacetone)palladiumOther

Conditions

Temperature
85 °C

Workup

  1. additionKeep Filtrate

Sources & evidence

ORD record
ord-ec198f10c6b54c69a55df9579fdfe8d7
Source dataset
Styrene Mizoroki-Heck

Reaction notes

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